{"id":7485,"date":"2024-04-02T16:01:01","date_gmt":"2024-04-02T08:01:01","guid":{"rendered":""},"modified":"2024-04-02T16:01:01","modified_gmt":"2024-04-02T08:01:01","slug":"DMPQ2Iracac\u7ea2\u5149\u94f1(Ir)\u914d\u5408\u7269|Ir(dfbpy)2(bpy)+PF6-|Ir(dfbpy)2(pyq)+PF6-|Ir(dfbpy)2(quqo)+PF6-\u79d1\u7814\u8bd5\u5242","status":"publish","type":"post","link":"https:\/\/mushiming.com\/7485.html","title":{"rendered":"DMPQ2Iracac\u7ea2\u5149\u94f1(Ir)\u914d\u5408\u7269|Ir(dfbpy)2(bpy)+PF6-|Ir(dfbpy)2(pyq)+PF6-|Ir(dfbpy)2(quqo)+PF6-\u79d1\u7814\u8bd5\u5242"},"content":{"rendered":"<p>DMPQ2Iracac\u7ea2\u5149\u94f1(Ir)\u914d\u5408\u7269|Ir(dfbpy)2(bpy)+PF6-|Ir(dfbpy)2(pyq)+PF6-|Ir(dfbpy)2(quqo)+PF6-\u79d1\u7814\u8bd5\u5242<\/p>\n<p style=\"margin-left:.0001pt;text-align:justify;\"><strong><strong>\u672c\u6587\u6240\u8ff0\u7684\u91d1\u5c5e\u914d\u5408\u7269\u8fd8\u53ef\u5408\u6210\u4e00\u7cfb\u5217\u7684(\u94f1Ir\u3001\u948cRu\u3001\u94b4\u3001\u954dNi\u3001\u94d5Eu\u3001\u94afPd\u3001\u94fdTb)\u7684\u914d\u5408\u7269\u53d1\u5149\u6750\u6599\uff0c\u5305\u62ec<\/strong><\/strong><strong><strong>Ir(ppy)2 (acac)\/Ir(pbi)2 (acac)\/Ir(bt)2 (acac)\/Ir(piq)2 (acac)\/\u4e09[2-(24-\u4e8c\u6c1f\u82ef\u57fa)\u5421\u5576]\u94f1(III)\/\u4e09[2-\u5bf9\u7532\u82ef\u57fa\u5421\u5576-c2n']\u94f1(iii)\/\u4e09[3-(5-\u7532\u57fa-2-\u5421\u5576\u57fa-kn)[11'-\u8054\u82ef\u57fa]-4-\u57fa-kc]\u5408\u94f1(iii)\/fac-ir((3-tbu-phenyl)-4-tbu\/IR(2-PHQ)2(ACAC)\/ITIC-4F\/Ru(bpz)3(Cl)2\/Ru(bpy)3Cl2\/Ru(bpy)3(BF4)2\/Ru(bpy)3(PF6)2\/Ru(bpz)3(PF6)2\/Ru(bpm)3Cl2\/Ru(bpm)3(PF6)2\/Ru(phen)3(PF6)2\/Ru(bpy)2(5-amino-Phen)(PF6)2\/Ru(phen)(bpy)2(PF6)2\/\u4e8c(22'-\u8054\u5421\u5576)(22'-\u8054\u5421\u55ea[510]\u5e76\u82ef\u57fa)\u948c\u4e8c\/Ru(bpy)2(phen-5-NH2)(PF6)2\/(Ir[dF(CF3)ppy]2(dtbpy))PF6\/(Ir[dF(CF3)ppy]2(Phen))PF6\/(Ir[dFCF3ppy]2(bpy))PF6\/(Ir[dFppy]2(bpy))PF6\/(Ir[dFppy]2(dtbpy))PF6\/(Ir[p-Fppy]2(bpy))PF6\/(Ir[p-Fppy]2(dtbpy))PF6\/(Ir[4-t-Bu-Phenyl-4-t-Bu-Py]2(dtbpy))PF6\/(Ir[dF(Me)ppy]2(dtbpy))PF6\/Ir(ppy)2(dtbbpy)PF6\/(Ir[dF(F)ppy]2(dCF3))PF6\/[Ir(ppy)2(bpy)]PF6\/Ir[p-F(Me)ppy]2(dtbbpy)PF6\/Fac-Ir(dFppy)3\/Fac-Ir[d-F(p-t-Bu)ppy]3\/Fac-Ir(p-CF3ppy)3\/Fac-Ir(p-Fppy)3\/Fac-Ir(p-tBu-ppy)3\/Fac-Ir(d-Fppy)3\/Fac-Ir((3-tBu-phenyl)-4-tBu-py))3\/Fac-Ir(3-tBu-ppy)3\/\u4e09[2-(2,4-\u4e8c\u6c1f\u82ef\u57fa)\u5421\u5576]\u94f1(III)\/\u4e09[1-(2,6-\u4e8c\u7532\u57fa\u82ef\u57fa)-2-\u82ef\u57fa-1H-\u54aa\u5511]\u5408\u94f1(III)\/\u4e09[1-(2,6-\u4e8c\u5f02\u4e19\u57fa\u82ef\u57fa)-2-\u82ef\u57fa-1H-\u54aa\u5511]\u5408\u94f1\/\u4e09[2-[1-[3,5-\u4e8c\u5f02\u4e19\u57fa[1,1'-\u8054\u82ef]-4-\u57fa]-1H-\u54aa\u5511-2-\u57fa]\u82ef\u57fa]\u94f1\/\u4e09(2-\u82ef\u57fa\u5421\u5576)\u5408\u94f1<\/strong><\/strong><strong><strong>\u4e09[2-(\u5bf9\u7532\u82ef\u57fa)\u5421\u5576-C2,N]\u5408\u94f1(III)\u7b49\u3002<\/strong><\/strong><\/p>\n<p style=\"margin-left:.0001pt;text-align:justify;\"><strong><strong>\u65b0\u578b\u7ea2\u5149\u94f1(Ir)\u914d\u5408\u7269\u7684\u7535\u81f4\u53d1\u5149\u7814\u7a76<\/strong><\/strong><\/p>\n<p style=\"margin-left:.0001pt;text-align:justify;\">&nbsp; &nbsp; \u5408\u6210\u4e86\u4e00\u79cd\u65b0\u578b\u7684Ir\u914d\u5408\u7269Bis(2-(3,5-dimethylphenyl)quinoline-C2,N)(acetylacetonato)iridium(\u2162)(\u7ed3\u6784\u5982\u56feDMPQ2Iracac),\u8be5\u914d\u5408\u7269\u4e0e\u7ecf\u5178\u7684\u6854\u7ea2\u78f7\u5149\u914d\u5408\u7269PQ2Iracac\u76f8\u6bd4,\u5728\u914d\u4f53\u7684\u82ef\u73af\u4e0a\u5f15\u5165\u4e86\u4e24\u4e2a\u63a8\u7535\u5b50\u7532\u57fa\u57fa\u56e2,\u5927\u5927\u6539\u5584\u4e86\u914d\u5408\u7269\u7ea2\u5149\u6027\u80fd,\u5149\u8c31\u7ea2\u79fb\u8d85\u8fc720nm\u4e14\u534a\u5cf0\u5bbd\u51cf\u5c0f\u4e8612 nm,\u7532\u57fa\u7684\u5f15\u5165\u8fd8\u589e\u52a0\u4e86\u7a7a\u95f4\u4f4d\u963b\u53ca\u5206\u5b50\u521a\u6027,\u6709\u6548\u6291\u5236\u78f7\u5149\u6750\u6599\u53d1\u5149\u8fc7\u7a0b\u4e2d\u7684\u6d53\u5ea6\u731d\u706d\u53ca\u63d0\u5347\u4e86\u53d1\u5149\u6548\u7387.\u91c7\u7528\u8be5\u78f7\u5149\u914d\u5408\u7269\u5236\u5907\u4e86\u7ed3\u6784\u4e3a:ITO\/NPB\/CBP:DMPQ2Iracac\/BCP\/Alq3\/LiF\/Al\u7684OLED\u5668\u4ef6,\u6d4b\u8bd5\u8868\u660e\u5f53\u63ba\u6742\u6d53\u5ea6\u4e3a7%\u65f6,OLED\u53d1\u5149\u4e3b\u5cf0\u4f4d\u4e3a620nm,\u534a\u5cf0\u5bbd\u4ec5\u4e3a59nm,\u8272\u5750\u6807\u4e3a(0.662,0.334),\u5668\u4ef6\u572810V\u65f6\u4eae\u5ea6\u8fbe\u52301400cd\/m2,\u8f83\u5927\u7535\u6d41\u6548\u7387\u8fbe\u52304.2cd\/A,\u8868\u660e\u8be5\u7ea2\u5149\u78f7\u5149\u914d\u5408\u7269\u5728OLED\u663e\u793a\u4e0e\u7167\u660e\u9886\u57df\u5c06\u6709\u8f83\u597d\u7684\u5b9e\u7528\u524d\u666f.<\/p>\n<p style=\"margin-left:.0001pt;text-align:justify;\"><img decoding=\"async\" src=\"https:\/\/img.mushiming.top\/app\/mushiming_com\/6ce1b5e26fea411eb7a64a6081a7e50d.png\" =\"\" =\"\" alt=\"DMPQ2Iracac\u7ea2\u5149\u94f1(Ir)\u914d\u5408\u7269|Ir(dfbpy)2(bpy)+PF6-|Ir(dfbpy)2(pyq)+PF6-|Ir(dfbpy)2(quqo)+PF6-\u79d1\u7814\u8bd5\u5242 (https:\/\/mushiming.com\/)  \u7b2c1\u5f20\" title=\"DMPQ2Iracac\u7ea2\u5149\u94f1(Ir)\u914d\u5408\u7269|Ir(dfbpy)2(bpy)+PF6-|Ir(dfbpy)2(pyq)+PF6-|Ir(dfbpy)2(quqo)+PF6-\u79d1\u7814\u8bd5\u5242  \u7b2c1\u5f20-\u7a46\u4e16\u660e\u535a\u5ba2\" ><\/p>\n<p>&nbsp;<\/p>\n<p style=\"margin-left:.0001pt;text-align:justify;\">\u82ef\u57fa\u564c\u5549\u7c7b\u94f1\u914d\u5408\u7269<\/p>\n<p style=\"margin-left:.0001pt;text-align:justify;\">\u82ef\u57fa\u564c\u5549\u73af\u91d1\u5c5e\u94f1\u914d\u5408\u7269(dpci)2Ir(pic)<\/p>\n<p style=\"margin-left:.0001pt;text-align:justify;\">\u4e2d\u6027\u73af\u91d1\u5c5e\u94f1\u914d\u5408\u7269Ir(dpci)2{H2B(mt)2}<\/p>\n<p style=\"margin-left:.0001pt;text-align:justify;\">\u82ef\u57fa\u55b9\u5549\u2014\u94f1\u914d\u5408\u7269<\/p>\n<p style=\"margin-left:.0001pt;text-align:justify;\">(dpq)2Ir(acac),cas848127-98-0<\/p>\n<p style=\"margin-left:.0001pt;text-align:justify;\">(dpq-OCH_3)_2Ir(acac)<\/p>\n<p style=\"margin-left:.0001pt;text-align:justify;\">(dpq-NO_2)_2Ir(acac)<\/p>\n<p style=\"margin-left:.0001pt;text-align:justify;\">(dpq-2Cl)_2Ir(acac)<\/p>\n<p style=\"margin-left:.0001pt;text-align:justify;\">Ir(dpq-5F)2(acac)<\/p>\n<p style=\"margin-left:.0001pt;text-align:justify;\">Ir(dpq-5CH3)2(acac)<\/p>\n<p style=\"margin-left:.0001pt;text-align:justify;\">Ir(dpq-5OCH3)2(acac)<\/p>\n<p style=\"margin-left:.0001pt;text-align:justify;\">Ir(III)\u91d1\u5c5e\u914d\u5408\u7269<\/p>\n<p style=\"margin-left:.0001pt;text-align:justify;\">[TpMe2Ir(acac)(C2H5)]<\/p>\n<p style=\"margin-left:.0001pt;text-align:justify;\">[TpMe2Ir(acac)(H)]<\/p>\n<p style=\"margin-left:.0001pt;text-align:justify;\">[TpMe2Ir(C9H14O2)]<\/p>\n<p style=\"margin-left:.0001pt;text-align:justify;\">[Tp3-Br,Me2Ir(3-Br-acac)Br]<\/p>\n<p style=\"margin-left:.0001pt;text-align:justify;\">[TpMe2Ir(3-NO2-acac)(C2H5)]<\/p>\n<p style=\"margin-left:.0001pt;text-align:justify;\">[TpMe2Ir(C2H4)(acac)(C2H3)]<\/p>\n<p style=\"margin-left:.0001pt;text-align:justify;\">Ir(acac){C[CH(OCH3)OSiPh2]<\/p>\n<p style=\"margin-left:.0001pt;text-align:justify;\">\u9ec4\u8272\u78f7\u5149\u94f1\u914d\u5408\u7269(F-BT)2Ir(acac)<\/p>\n<p style=\"margin-left:.0001pt;text-align:justify;\">(F-BT)2Ir(3F-acac)<\/p>\n<p style=\"margin-left:.0001pt;text-align:justify;\">(F-BT)2Ir(6F-acac)<\/p>\n<p style=\"margin-left:.0001pt;text-align:justify;\">\u78f7\u5149\u94f1\u914d\u5408\u7269Ir(BPBM)2(acac)<\/p>\n<p style=\"margin-left:.0001pt;text-align:justify;\">Ir(MBPBM)2(acac)<\/p>\n<p style=\"margin-left:.0001pt;text-align:justify;\">Ir(DABPBM)2(acac)<\/p>\n<p style=\"margin-left:.0001pt;text-align:justify;\">Ir(TPAPBM)2(acac)<\/p>\n<p style=\"margin-left:.0001pt;text-align:justify;\">Ir(ECPBM)2(acac)<\/p>\n<p style=\"margin-left:.0001pt;text-align:justify;\">\u53d1\u84dd\u8272\u78f7\u5149\u7684\u94f1\u914d\u5408(ppy)2Ir(POP)PF6<\/p>\n<p style=\"margin-left:.0001pt;text-align:justify;\">\u7ea2\u8272\u78f7\u5149\u94f1\u914d\u5408\u7269Ir(ppy)2(NBT)<\/p>\n<p style=\"margin-left:.0001pt;text-align:justify;\">\u7ea2\u8272\u94d5\u914d\u5408\u7269Eu(DBM)3(FPIP)\u3001Eu(DBM)3(EFPIP)<\/p>\n<p style=\"margin-left:.0001pt;text-align:justify;\">\u542b\u4e09\u6c1f\u7532\u57fa\u73af\u94c2(\u2161)\u914d\u5408\u7269<\/p>\n<p style=\"margin-left:.0001pt;text-align:justify;\">\u5c0f\u7f16\uff1awyf 02.10<\/p>\n","protected":false},"excerpt":{"rendered":"DMPQ2Iracac\u7ea2\u5149\u94f1(Ir)\u914d\u5408\u7269|Ir(dfbpy)2(bpy)+PF6-|Ir(dfbpy)2(pyq)+PF6-|Ir(dfbpy)2(quqo)+PF6-\u79d1\u7814\u8bd5\u5242DMPQ2Iracac\u7ea2\u5149\u94f1(...","protected":false},"author":1,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[],"tags":[],"_links":{"self":[{"href":"https:\/\/mushiming.com\/wp-json\/wp\/v2\/posts\/7485"}],"collection":[{"href":"https:\/\/mushiming.com\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/mushiming.com\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/mushiming.com\/wp-json\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/mushiming.com\/wp-json\/wp\/v2\/comments?post=7485"}],"version-history":[{"count":0,"href":"https:\/\/mushiming.com\/wp-json\/wp\/v2\/posts\/7485\/revisions"}],"wp:attachment":[{"href":"https:\/\/mushiming.com\/wp-json\/wp\/v2\/media?parent=7485"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/mushiming.com\/wp-json\/wp\/v2\/categories?post=7485"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/mushiming.com\/wp-json\/wp\/v2\/tags?post=7485"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}